********************** **Chemical Potential** ********************** :: Chemical Potential = {IDEAL_SOLUTION | STOICHIOMETRIC_PHASE} ----------------------- **Description / Usage** ----------------------- This card is used to specify the formulation of the chemical potential for the phase. It is currently unconnected to *Goma’s* functionality. Two values are permissible: +--------------------------+-------------------------------------------------------------------------------------+ |**IDEAL_SOLUTION** |Ideal solution thermodynamics | +--------------------------+-------------------------------------------------------------------------------------+ |**STOICHIOMETRIC_PHASE** |Phase consists of fixed set of molecular composition | +--------------------------+-------------------------------------------------------------------------------------+ ------------ **Examples** ------------ Following is a sample card: :: Chemical Potential = IDEAL_SOLUTION ------------------------- **Technical Discussion** ------------------------- The chemical potential of species k in an ideal solution is given by the expression, [Denbigh, p. 249], .. figure:: /figures/457_goma_physics.png :align: center :width: 90% where μk*(T, P) is defined as the chemical potential of species k in its pure state (or a hypothetical pure state if a real pure state doesn’t exist) at temperature T and pressure P. μk*(T, P) is related to the standard state of species k in the phase, μk, o(T), which is independent of pressure, through specification of the pressure dependence of the pure species k. Xk is the mole fraction of species k in the phase. The chemical potential of species k (actually there is only one species!) in a stoichiometric phase is equal to .. figure:: /figures/458_goma_physics.png :align: center :width: 90% -------------- **References** -------------- Denbigh, K., The Principles of Chemical Equilibrium, 4th Ed., Cambridge University Press, 1981